SELECT 
  1 
FROM 
  cscart_lock_keys 
WHERE 
  key_id = '91c44611bac06deb469f562561f776191f896782baac41c49631b73032ae3ddb' 
  AND token = 'tJIRzx9EYuypXOyzF5IN3PgUAXlEB03vtQz4wpBha9U=' 
  AND expiry_at > UNIX_TIMESTAMP(NOW())

Query time 0.00026

Explain
id select_type table type possible_keys key key_len ref rows Extra
1 SIMPLE Impossible WHERE noticed after reading const tables