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SELECT 
  1 
FROM 
  cscart_lock_keys 
WHERE 
  key_id = '85592039f83418390be14c4fe2fa499c2d9597ba9871f8d29ef4e9afa7be78f2' 
  AND token = 'k5ynWCV7CukQS6FVAMqEXYPlSw1IQxJPG0LIWn27RNs=' 
  AND expiry_at > UNIX_TIMESTAMP(NOW())

Query time 0.00033

Explain
id	select_type	table	type	possible_keys	key	key_len	ref	rows	Extra
1	SIMPLE								Impossible WHERE noticed after reading const tables