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SELECT 
  1 
FROM 
  cscart_lock_keys 
WHERE 
  key_id = '7fa01dbcb3792ca4c12de666a3695a1a9a82deb0fcdfe9e6f9ce78325150ad19' 
  AND token = 'Hj8jrb2Cm9qKQgXshR9IcOipglgglQfRSczfs594Cms=' 
  AND expiry_at > UNIX_TIMESTAMP(NOW())

Query time 0.00018

Explain
id	select_type	table	type	possible_keys	key	key_len	ref	rows	Extra
1	SIMPLE								Impossible WHERE noticed after reading const tables