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SELECT 
  1 
FROM 
  cscart_lock_keys 
WHERE 
  key_id = 'eb738087d253e69b45dcaa94a125f0d2d7718a5b14ea96bdb03f33f8013e8b5f' 
  AND expiry_at > UNIX_TIMESTAMP(NOW())

Query time 0.00013

Explain
id	select_type	table	type	possible_keys	key	key_len	ref	rows	Extra
1	SIMPLE								Impossible WHERE noticed after reading const tables