SELECT 
  1 
FROM 
  cscart_lock_keys 
WHERE 
  key_id = '813c39856a10532e7a306336fe78555e8d02866c736321b82298726754b5cdd2' 
  AND token = 'OcME695LlXEUMk2+SuQTgh/GSX/q7uOeXOpHUA/HMt0=' 
  AND expiry_at > UNIX_TIMESTAMP(NOW())

Query time 0.00013

Explain
id select_type table type possible_keys key key_len ref rows Extra
1 SIMPLE Impossible WHERE noticed after reading const tables