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SELECT 
  1 
FROM 
  cscart_lock_keys 
WHERE 
  key_id = '4a09f196d1f6e61ab89b09a99c173e6cf264e22c896b2f92bb770f45f990987d' 
  AND token = 'el4BWWGkUXCR7BUlkpNyAXhHpD2KxV4bGaSgGVmopJw=' 
  AND expiry_at > UNIX_TIMESTAMP(NOW())

Query time 0.00028

Explain
id	select_type	table	type	possible_keys	key	key_len	ref	rows	Extra
1	SIMPLE								Impossible WHERE noticed after reading const tables