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SELECT 
  1 
FROM 
  cscart_lock_keys 
WHERE 
  key_id = 'b1039725e8ef5024a67b169f0cb111fd7729796276f834d1255c7ca798dad13f' 
  AND token = 'rbTvUmqQ4Jxeg8xN7qdwDoAFBc1Q1PN6CaDBpWyqH9I=' 
  AND expiry_at > UNIX_TIMESTAMP(NOW())

Query time 0.00017

Explain
id	select_type	table	type	possible_keys	key	key_len	ref	rows	Extra
1	SIMPLE								Impossible WHERE noticed after reading const tables