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SELECT 
  1 
FROM 
  cscart_lock_keys 
WHERE 
  key_id = '9119f54694f6a76d801e8d7bf00419c8811c48bc2a297b871a688084ff8cad4d' 
  AND token = 'TPd81lFKmuevPnTgrVesTZusQb6oooLBVDQCRk1fUNg=' 
  AND expiry_at > UNIX_TIMESTAMP(NOW())

Query time 0.00015

Explain
id	select_type	table	type	possible_keys	key	key_len	ref	rows	Extra
1	SIMPLE								Impossible WHERE noticed after reading const tables