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SELECT 
  1 
FROM 
  cscart_lock_keys 
WHERE 
  key_id = '9336df3623b125ea25c167ac3159235052c4972cfe6bb2214f83d29a7070e7ac' 
  AND token = 'LCE3xVrK3V9KMwUGkHrtrzMmZ5ZxWDt3pHM4RRHYTR8=' 
  AND expiry_at > UNIX_TIMESTAMP(NOW())

Query time 0.00023

Explain
id	select_type	table	type	possible_keys	key	key_len	ref	rows	Extra
1	SIMPLE								Impossible WHERE noticed after reading const tables