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SELECT 
  1 
FROM 
  cscart_lock_keys 
WHERE 
  key_id = '14a4005327d82c757c23ee6be17dda491de01c486a8dad2ae0b17e5f02141596' 
  AND token = 'B7KkIAzfwNcHBS2LzRAojbLPlZF0zTz0gcHx8VXy5cE=' 
  AND expiry_at > UNIX_TIMESTAMP(NOW())

Query time 0.00014

Explain
id	select_type	table	type	possible_keys	key	key_len	ref	rows	Extra
1	SIMPLE								Impossible WHERE noticed after reading const tables