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SELECT 
  1 
FROM 
  cscart_lock_keys 
WHERE 
  key_id = '1b7582a1a9b570c5670847e8d7adeabdab9d0e9319e9ccdeaeab0ebb432d31b4' 
  AND token = 'qqkrI4Vc9y3ZbslBdtCKNypHl8h0jTCZh8l2SJROTis=' 
  AND expiry_at > UNIX_TIMESTAMP(NOW())

Query time 0.00012

Explain
id	select_type	table	type	possible_keys	key	key_len	ref	rows	Extra
1	SIMPLE								Impossible WHERE noticed after reading const tables