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SELECT 
  1 
FROM 
  cscart_lock_keys 
WHERE 
  key_id = 'cdc8db7b5011985399ea2ef1937cb9a2429051944763c6032f2fb4fb3dfb96c3' 
  AND expiry_at > UNIX_TIMESTAMP(NOW())

Query time 0.00018

Explain
id	select_type	table	type	possible_keys	key	key_len	ref	rows	Extra
1	SIMPLE								Impossible WHERE noticed after reading const tables